Batch 40 — Raven Records

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Experiments / Batch 40

Batch 40 not OK

also written as LBN 40 · S 9076 #40 · 40

aminev

42.9

target 30.1 · +42.5% vs target

28.5

target 43.2 · -34.0% vs target

Application test

2 tests

Conclusion — verbatim from the source

“Tested against RED 57:1, BLUE 15:3, YELLOW 12 pigment ; yellow pigment gloss less while other RED & Blue pigment good”

Lab Batch 40.pdf, page 1

Aim

To develop product equivalent to reference product

Raw materials

#	Material	Source	Qty	Purity %
1	Surfol R-1400 R-188		150 g
2	P2O5	Commercial	4.88 g
3	Epomine SP-018	Nippon	90 g	100
4	2 ethyl hexyl acrylate		210 g	100

Process

Step

Conditions

Charged

What happened

Results

Step 1

Phosphate ester

28112025 9076 Expt Table 2025.xls · Lab Batch 40.pdf

temperature: 40 → 70-75 °C · ELN: 58-75 °Catmosphere: N2time: 0.2 + 3.5 h · ELN: 5 h

Surfol R-1400 R-188 150 g [ELN] / R-1400 R-188 (1000) 157 g [Table]

P2O5 4.88 g [ELN]

PPA ( 106 %) 5.74 g [Table]

Phosphate ester- RBF with R-1400 heated to 50 deg C and then slowly added Polyphosphoric acid followed by P2O5 into it under N2 atmosphere. Digested this for 3 hrs at 70-75 deg C. Cool to RT and filter through Nylon Mesh [ELN]

Appearance- yellowish clear [ELN]

Step-by-step (5 entries)

Time (h)	Temp (°C)	What happened
0.2	40	Table
3.5	70-75	Table
		RBF with SP-18 Table
10 min	79	AIBN 0.6 gm added, stirrerd Table
2 hr	79-81	Started feed 2 EH acrylate Table

AV 37

Step 2

Acrylate intermediate

28112025 9076 Expt Table 2025.xls · Lab Batch 40.pdf

temperature: 78-82 °Catmosphere: N2time: 3.5 + 5.5 h · ELN: 6.5 h

Epomine SP-018 90 g [ELN]

2 ethyl hexyl acrylate 210 g

AIBN 0.6 gm [Table]

Acrylate intermediate- RBF with Epomine SP- 018 heated to 78-81 deg C under N2 atmosphere. Slowly feed of 2-ethyl hexyl acrylate over 2 hrs and continue reaction for 5 hrs. Monitoring of reaction done by IV. At IV-25-35 Cool to [ELN; text ends here in the source]

Appearance- yellowish clear [ELN]

Step-by-step (2 entries)

Time (h)	Temp (°C)	Atm	What happened
3.5	78-82		Table
5.5	78-82		Table

IV 42IV 27.5AV 44.3

Step 3

Neutralization

28112025 9076 Expt Table 2025.xls · Lab Batch 40.pdf

temperature: 55-60 °C · ELN: 56-61 °Catmosphere: N2time: 25-30 min (feed of Step-I) · ELN: 3.5 h

Step - 2 Product 20 gm [Table]

Neutralization - RBF with acrylate intermediate of step-2) (20%) heated to 56 deg C under N2 atmosphere. Slowly feed of step-1) (80%) Phosphate ester into it over 30 min and continue to RT and filter through Nylon Mesh. [ELN]

Step-by-step (1 entry)

Time (h)	Temp (°C)	Atm	What happened
25-30 min (feed)	55-60		feeding of Step-I over 25-30 min Table

AV 28.5SAP 52HV 74Amine 42.9IV 6.8AV 1.5SAP 204HV 183Amine 285IV 27.5

Step 1 — Phosphate ester curated · 2 sources

temperature: 40 → 70-75 °C · ELN: 58-75 °C atmosphere: N2 time: 0.2 + 3.5 h · ELN: 5 h

Charged Surfol R-1400 R-188 150 g [ELN] / R-1400 R-188 (1000) 157 g [Table]P2O5 4.88 g [ELN]PPA ( 106 %) 5.74 g [Table]

AV 37

Appearance- yellowish clear [ELN]

Step-by-step (5 entries)

Time (h)	Temp (°C)	What happened
0.2	40		Table
3.5	70-75		Table
		RBF with SP-18	Table
10 min	79	AIBN 0.6 gm added, stirrerd	Table
2 hr	79-81	Started feed 2 EH acrylate	Table

View each source separately (28112025 9076 Expt Table 2025.xls · Lab Batch 40.pdf)

as recorded in 28112025 9076 Expt Table 2025.xls:

temperature: 40; 70-75time_h: 0.2 h; 3.5 h

Charged: R-1400 R-188 · PPA

{'type': 'note', 'text': "Step 1 'Other' column holds prose, not results: 'RBF with SP-18', 'AIBN 0.6 gm added', 'Started feed 2 EH acrylate'. Carried as procedure events, not dropped."}; {'type': 'note', 'text': "Material 1 name cell reads 'R-1400 R-188 (1000)'; the '(1000)' suffix is part of the name cell, not a separate quantity."}

as recorded in Lab Batch 40.pdf:

Step-by-step (1 entry)

Time (h)	Temp (°C)	Atmosphere	What happened
0.2 h; 3.5 h	40; 70-75		Phosphate ester- RBF with R-1400 heated to 50 deg C and then slowly added Polyphosphoric acid followed by P2O5 into it under N2 atmosphere. Digested this for 3 hrs at 70-75 deg C. Cool to RT and filter through Nylon Mesh AV-37

Appearance- yellowish clear

Step 2 — Acrylate intermediate curated · 2 sources

temperature: 78-82 °C atmosphere: N2 time: 3.5 + 5.5 h · ELN: 6.5 h

Charged Epomine SP-018 90 g [ELN]2 ethyl hexyl acrylate 210 gAIBN 0.6 gm [Table]

IV 42 IV 27.5 AV 44.3

Appearance- yellowish clear [ELN]

Step-by-step (2 entries)

Time (h)	Temp (°C)	Atmosphere	What happened
3.5	78-82			Table
5.5	78-82			Table

View each source separately (28112025 9076 Expt Table 2025.xls · Lab Batch 40.pdf)

as recorded in 28112025 9076 Expt Table 2025.xls:

temperature: 78-82time_h: 3.5 h; 5.5 h

Charged: 2 ethyl hexyl acrylate · AIBN

iodine_value 42 iodine_value 27.5 acid_value 44.3

as recorded in Lab Batch 40.pdf:

Step-by-step (1 entry)

Time (h)	Temp (°C)	Atmosphere	What happened
3.5 h; 5.5 h	78-82		Acrylate intermediate- RBF with Epomine SP- 018 heated to 78-81 deg C under N2 atmosphere. Slowly feed of 2-ethyl hexyl acrylate over 2 hrs and continue reaction for 5 hrs. Monitoring of reaction done by IV. At IV-25-35 Cool to

Appearance- yellowish clear

Step 3 — Neutralization curated · 2 sources

temperature: 55-60 °C · ELN: 56-61 °C atmosphere: N2 time: 25-30 min (feed of Step-I) · ELN: 3.5 h

Charged Step - 2 Product 20 gm [Table]

AV 28.5 SAP 52 HV 74 Amine 42.9 IV 6.8 AV 1.5 SAP 204 HV 183 Amine 285 IV 27.5

Step-by-step (1 entry)

Time (h)	Temp (°C)	Atmosphere	What happened
25-30 min (feed)	55-60		feeding of Step-I over 25-30 min	Table

View each source separately (28112025 9076 Expt Table 2025.xls · Lab Batch 40.pdf)

as recorded in 28112025 9076 Expt Table 2025.xls:

temperature: 55-60time_h: 25-30 min (feed of Step-I)

Charged: Step - 2 Product

acid_value 1.5 saponification_value 204 hv 183 amine_value 285 iodine_value 27.5

{'type': 'note', 'text': "Step 3 material reads 'Step - 2 Product' with Qty '20 gm' and a feed event 'feeding of Step-I over 25-30 min'. The named material (Step-2 product) and the feed source (Step-I) do not agree; copied verbatim as printed."}; {'type': 'note', 'text': 'Step 3 A.V. column is a multi-value result string (AV/SAP/HV/Amine/IV); all values emitted as measurements.'}

as recorded in Lab Batch 40.pdf:

Step-by-step (1 entry)

Time (h)	Temp (°C)	Atmosphere	What happened
25-30 min (feed of Step-I)	55-60		Neutralization - RBF with acrylate intermediate of step-2) (20%) heated to 56 deg C under N2 atmosphere. Slowly feed of step-1) (80%) Phosphate ester into it over 30 min and continue to RT and filter through Nylon Mesh.

AV-28.5/SAP-52/ HV-74/Amine-42.9/ IV-6.8

Critical parameters — measured vs target

Parameter	Target	Measured
aminev	30.1	42.9
av	43.2	28.5

Sample unspecified sample

OK (RED 57:1 pigment)

good

OK (BLUE 15:3 pigment)

good

result (YELLOW 12 pigment)

yellow pigment gloss less

Sample S 9076 #40

result Violet 23 (NC-PU ink)

Parameter	This sample	Standard (BYK 9076 Standard)
Viscosity	40 sec	35 sec
Gloss	55.5	58.8
Colour Strength	1	1
Resolubility	4	4
Transparency	Eq. to Std	Ref as Std

APP DATA- BYK 9076 equivalent.xlsx

result Violet 27 (NC-PU ink)

Parameter	This sample	Standard (BYK 9076 Standard)
Viscosity	42 sec	37 sec
Gloss	6.5	6.9
Colour Strength	1	1
Resolubility	4	4
Transparency	Eq to Std	Ref as Std

APP DATA- BYK 9076 equivalent.xlsx

result Black (NC-PU ink)

Parameter	This sample	Standard (BYK 9076 Standard)
Viscosity	25 sec	23 sec
Gloss	46.4	46.8
Colour Strength	1	1
Resolubility	3	4
Transparency	Eq to Std	Ref as Std

APP DATA- BYK 9076 equivalent.xlsx

result Blue (NC-PU ink)

Parameter	This sample	Standard (BYK 9076 Standard)
Viscosity	24 sec	22 sec
Gloss	36.2	36.3
Colour Strength	1	1
Resolubility	4	4
Transparency	Eq to std	Ref as Std

APP DATA- BYK 9076 equivalent.xlsx

Where this record comes from

Lab Batch 40.pdf — lab journal (primary source)

APP DATA- BYK 9076 equivalent.xlsx — application testing

28112025 9076 Expt Table 2025.xls — researcher summary (cross-check)

Something wrong on this page? Record a correction

Your correction is permanent: it survives every re-extraction and the field can no longer be changed by the system.

Field-by-field provenance (18 fields) — for auditors

3 extraction fragments · merged 2026-08-25 · 0 human-validated fields

Fix a wrong or missing extraction side-by-side with the original: qwen-extract--lab-batch-40--lbn-40 app-data--S 9076 #40 expt-block--40

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materials[0]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
materials[1]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
materials[2]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
materials[3]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
process_steps[0]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	medium
process_steps[1]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	medium
process_steps[2]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	medium
critical_parameters[0]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
critical_parameters[1]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
samples[0]	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
outcome	Lab Batch 40.pdf page 1	qwen-tasks/extract-fragment.md@unversioned	high
samples[1]	APP DATA- BYK 9076 equivalent.xlsx sheet BYK_9076_equivalent, rows 62-62	parse_app_data.py@unversioned	high
record_type	28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '40', csv rows 354-361	qwen-tasks/extract-expt-block.md@unversioned	high
process_steps[3]	28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '40', csv rows 354-361	qwen-tasks/extract-expt-block.md@unversioned	high
process_steps[4]	28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '40', csv rows 354-361	qwen-tasks/extract-expt-block.md@unversioned	high
process_steps[5]	28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '40', csv rows 354-361	qwen-tasks/extract-expt-block.md@unversioned	high

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    {
      "file": "pdf/9076 Data for Raven POC project/Old ELN/Lab Batch 40.pdf",
      "role": "eln_report",
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      "link_status": "rule"
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  "aim": "To develop product equivalent to reference product",
  "conclusion": "Tested against RED 57:1, BLUE 15:3, YELLOW 12 pigment ; yellow pigment gloss less while other RED & Blue pigment good",
  "materials": [
    {
      "sr_no": "1",
      "name": "Surfol R-1400 R-188",
      "source": "",
      "quantity": "150",
      "unit": "g"
    },
    {
      "sr_no": "2",
      "name": "P2O5",
      "source": "Commercial",
      "quantity": "4.88",
      "unit": "g"
    },
    {
      "sr_no": "3",
      "name": "Epomine SP-018",
      "source": "Nippon",
      "quantity": "90",
      "unit": "g",
      "purity_pct": "100"
    },
    {
      "sr_no": "4",
      "name": "2 ethyl hexyl acrylate",
      "source": "",
      "quantity": "210",
      "unit": "g",
      "purity_pct": "100"
    }
  ],
  "process_steps": [
    {
      "step": 1,
      "time": "5",
      "temperature": "58-75",
      "atmosphere": "N2",
      "procedure": [
        {
          "action": "Phosphate ester- RBF with R-1400 heated to 50 deg C and then slowly added Polyphosphoric acid followed by P2O5 into it under N2 atmosphere. Digested this for 3 hrs at 70-75 deg C. Cool to RT and filter through Nylon Mesh AV-37"
        }
      ],
      "remarks": "Appearance- yellowish clear"
    },
    {
      "step": 2,
      "time": "6.5",
      "temperature": "78-82",
      "atmosphere": "N2",
      "procedure": [
        {
          "action": "Acrylate intermediate- RBF with Epomine SP- 018 heated to 78-81 deg C under N2 atmosphere. Slowly feed of 2-ethyl hexyl acrylate over 2 hrs and continue reaction for 5 hrs. Monitoring of reaction done by IV. At IV-25-35 Cool to"
        }
      ],
      "remarks": "Appearance- yellowish clear"
    },
    {
      "step": 3,
      "time": "3.5",
      "temperature": "56-61",
      "atmosphere": "N2",
      "procedure": [
        {
          "action": "Neutralization - RBF with acrylate intermediate of step-2) (20%) heated to 56 deg C under N2 atmosphere. Slowly feed of step-1) (80%) Phosphate ester into it over 30 min and continue to RT and filter through Nylon Mesh."
        }
      ],
      "remarks": "AV-28.5/SAP-52/ HV-74/Amine-42.9/ IV-6.8"
    },
    {
      "step": 1,
      "materials": [
        {
          "name": "R-1400  R-188",
          "qty_g": "157",
          "role": "reactant",
          "verbatim": "R-1400  R-188  (1000)"
        },
        {
          "name": "PPA",
          "qty_g": "5.74",
          "role": "reactant",
          "verbatim": "PPA ( 106 %)"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "type": "temperature",
          "temperature": "40",
          "time_h": "0.2",
          "verbatim": "40 / 0.2"
        },
        {
          "seq": 2,
          "type": "temperature",
          "temperature": "70-75",
          "time_h": "3.5",
          "verbatim": "70-75 / 3.5"
        },
        {
          "seq": 3,
          "type": "condition",
          "verbatim": "RBF with SP-18"
        },
        {
          "seq": 4,
          "type": "addition",
          "temperature": "79 deg C",
          "time_h": "10 min",
          "event": "AIBN  0.6 gm added",
          "verbatim": "AIBN  0.6 gm added ,79 deg C,10 min stirrerd"
        },
        {
          "seq": 5,
          "type": "feed",
          "temperature": "79-81",
          "time_h": "2 hr",
          "event": "Started feed 2 EH acrylate",
          "verbatim": "Started feed 2 EH acrylate,79-81,2 hr"
        }
      ],
      "conditions": {
        "temperature": "40; 70-75",
        "time_h": "0.2 h; 3.5 h"
      },
      "results": [],
      "remarks": "{'type': 'note', 'text': \"Step 1 'Other' column holds prose, not results: 'RBF with SP-18', 'AIBN 0.6 gm added', 'Started feed 2 EH acrylate'. Carried as procedure events, not dropped.\"}; {'type': 'note', 'text': \"Material 1 name cell reads 'R-1400  R-188  (1000)'; the '(1000)' suffix is part of the name cell, not a separate quantity.\"}"
    },
    {
      "step": 2,
      "materials": [
        {
          "name": "2 ethyl hexyl acrylate",
          "qty_g": "210",
          "role": "reactant",
          "verbatim": "ii)   2 ethyl hexyl acrylate"
        },
        {
          "name": "AIBN",
          "qty_g": "0.6 gm",
          "role": "reactant",
          "verbatim": "iii) AIBN"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "type": "temperature",
          "temperature": "78-82",
          "time_h": "3.5",
          "verbatim": "78-82 / 3.5"
        },
        {
          "seq": 2,
          "type": "temperature",
          "temperature": "78-82",
          "time_h": "5.5",
          "verbatim": "78-82 / 5.5"
        }
      ],
      "conditions": {
        "temperature": "78-82",
        "time_h": "3.5 h; 5.5 h"
      },
      "results": [
        {
          "parameter": "iodine_value",
          "value": "42",
          "verbatim": "IV- 42"
        },
        {
          "parameter": "iodine_value",
          "value": "27.5",
          "verbatim": "IV- 27.5"
        },
        {
          "parameter": "acid_value",
          "value": "44.3",
          "note": "polysemous 'A.V.' cell of Step 2 (also carries Step 1 acid value by elimination)",
          "verbatim": "AV-44.3"
        }
      ],
      "remarks": ""
    },
    {
      "step": 3,
      "materials": [
        {
          "name": "Step - 2 Product",
          "qty_g": "20 gm",
          "role": "intermediate",
          "verbatim": "Step -  2 Product"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "type": "temperature",
          "temperature": "55-60",
          "event": "feeding of Step-I over 25-30 min",
          "verbatim": "55-60,feeding of Step-I over 25-30 min"
        }
      ],
      "conditions": {
        "temperature": "55-60",
        "time_h": "25-30 min (feed of Step-I)"
      },
      "results": [
        {
          "parameter": "acid_value",
          "value": "1.5",
          "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
        },
        {
          "parameter": "saponification_value",
          "value": "204",
          "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
        },
        {
          "parameter": "hv",
          "value": "183",
          "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
        },
        {
          "parameter": "amine_value",
          "value": "285",
          "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
        },
        {
          "parameter": "iodine_value",
          "value": "27.5",
          "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
        }
      ],
      "remarks": "{'type': 'note', 'text': \"Step 3 material reads 'Step -  2 Product' with Qty '20 gm' and a feed event 'feeding of Step-I over 25-30 min'. The named material (Step-2 product) and the feed source (Step-I) do not agree; copied verbatim as printed.\"}; {'type': 'note', 'text': 'Step 3 A.V. column is a multi-value result string (AV/SAP/HV/Amine/IV); all values emitted as measurements.'}"
    }
  ],
  "critical_parameters": [
    {
      "parameter": "aminev",
      "reference_value": "30.1",
      "value": "42.9"
    },
    {
      "parameter": "av",
      "reference_value": "43.2",
      "value": "28.5"
    }
  ],
  "samples": [
    {
      "application_tests": [
        {
          "system": "RED 57:1 pigment",
          "result": "good",
          "verdict": "ok"
        },
        {
          "system": "BLUE 15:3 pigment",
          "result": "good",
          "verdict": "ok"
        },
        {
          "system": "YELLOW 12 pigment",
          "result": "yellow pigment gloss less"
        }
      ],
      "sample_id": "unspecified sample"
    },
    {
      "sample_id": "S 9076 #40",
      "application_tests": [
        {
          "test": "Violet 23",
          "system": "NC-PU ink",
          "conditions": "trial 05.04.2025",
          "result": "Viscosity: 40 sec; Gloss: 55.5; Colour Strength: 1; Resolubility: 4; Transparency: Eq. to Std",
          "vs_reference": "BYK 9076 Standard — Viscosity: 35 sec; Gloss: 58.8; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
          "file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
        },
        {
          "test": "Violet 27",
          "system": "NC-PU ink",
          "conditions": "trial 05.04.2025",
          "result": "Viscosity: 42 sec; Gloss: 6.5; Colour Strength: 1; Resolubility: 4; Transparency: Eq to Std",
          "vs_reference": "BYK 9076 Standard — Viscosity: 37 sec; Gloss: 6.9; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
          "file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
        },
        {
          "test": "Black",
          "system": "NC-PU ink",
          "conditions": "trial 05.04.2025",
          "result": "Viscosity: 25 sec; Gloss: 46.4; Colour Strength: 1; Resolubility: 3; Transparency: Eq to Std",
          "vs_reference": "BYK 9076 Standard — Viscosity: 23 sec; Gloss: 46.8; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
          "file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
        },
        {
          "test": "Blue",
          "system": "NC-PU ink",
          "conditions": "trial 05.04.2025",
          "result": "Viscosity: 24 sec; Gloss: 36.2; Colour Strength: 1; Resolubility: 4; Transparency: Eq to std",
          "vs_reference": "BYK 9076 Standard — Viscosity: 22 sec; Gloss: 36.3; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
          "file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
        }
      ]
    }
  ],
  "outcome": {
    "status": "not ok",
    "basis": "Tested against RED 57:1, BLUE 15:3, YELLOW 12 pigment ; yellow pigment gloss less while other RED & Blue pigment good",
    "citation": "Lab Batch 40.pdf, page 1"
  },
  "record_type": "synthesis"
}