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Sheet · 28112025 9076 Expt Table 2025.converted_sheet_9076_Experiments.csv — rows 324–401 of 400 · cited row highlighted

(P-1.2 %)76-780.5 hr feed ove\nr slight yellow\n tincture, clear\n transparent mass30 min55Feed of Phosphate (50%) clear mass
AV-39.65/ SAP-40.4878-791 hr clear transparent with slight yellow tincture\n // Feed over20 min550.3yellow brownish clear
10 min5620 % feed completedviscosity incresed
78-812 hr clear\n transparent\n yellow tincture \nreaction mass.AV-0.3/ Amine-290.5/\n IV-30/HV-218.141.5 hr57-58stirrer well
78-812 hr clear transparent increase\n yellow tincture \nreaction mass.3 hr IV-45\n6.5 IV 30\nCoolAV-33.2/SAP-59.4/Amine- \n/ HV-70.5/IV-8.7
38Ci) Surfol R-1400 HV-36.8 (R-83/)226540.5i) Lupasol G-20 WFStep - 1 Product(160(80%)AV-43.1
ii) PolyPhosphoric acid (102%)4.023561ii) 2 ethyl hexyl acrylateSame as in\n LBN-38 DStep - 2 Product( L-2) 40 (20%)
ii) Phosphorous pentaoxide3.14681.5AV-43.11055Stirre wellN-2yellowish
(P-1.2 %)15min55Feed of Phosphate (50%) clear mass
20 min55feed completedyellow brownish clear
PPA feed at 55 deg C for 10 min55 deg72-76 deg 45 minviscosity incresed
P2O5 feed at 55 deg C for 10 min5576-781.5 hrAV-0.3/ Amine-290.5/\n IV-30/HV-218.141.5 hr57-58stirrer wellAV-36.9/ SAP-50.6/HV71.89/ IV-7.377\nAmine-47.5
Cool
39i) Surfol R-1400 / MW 1500 ( 2 kg) \nR-188265540.5i) Epomine SP- 01890Step - 1 Product240AV-35.5
ii) PolyPhosphoric acid (106%)4.67562.5ii) 2 ethyl hexyl acrylate210Step - 2 Product 60
ii) Phosphorous pentaoxide3.65682iii) AIBN0.6 gm55Stirre wellN-2
30 min55Feed of Phosphate N-2
PPA feed at 55 deg C for 10 min550.1RBF with SP-187910 min 55Turbidity foundN-2
772.5AIBN 0.6 gm added 79 deg C10 min stirrerd30 min55Turbidity reduced N-2
Started feed 2 EH acrylate79-812 hr30 min58Turbidity reduced N-2
P2O5 feed at 55 deg C for 10 min550.178-823.5IV- 423057-59Found foam in\n reaction massN-2
75-782.5AV-35.6/\n SAP39.5/\nHV-37.678-825.5IV- 27.5AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.51.5 hr57-59Found foam at\n top of mass AV-29.67/SAP-71.87/\nHV-44.67/Amine-46.5/\nIV-9.4
After ward heated on heating mantle 82-851.5 hrCool to RT
i) Epomine SP- 01890Step - 1 Product80 gm
40R-1400 R-188 (1000)157400.2ii) 2 ethyl hexyl acrylate210Step - 2 Product 20 gm55-60feeding of Step-I over 25-30 min
PPA ( 106 %)5.7470-753.5AV-44.3iii) AIBN0.6 gm
RBF with SP-1879
AIBN 0.6 gm added 79 deg C10 min stirrerd
Started feed 2 EH acrylate79-812 hr
78-823.5IV- 42
78-825.5IV- 27.5AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5
41i) Esteem BEP 1450 ( HV-40 LOD-3.1 %) / Lot-2505013A/ R-2433350 gm450.2 Epomine SP- 01822574-812FeedStep - 1 Product\nPhosphate 0.8
05.06.25ii) Phosphorous pentaoxide13 gm70-751Found coagulant later on dispersed2 ethyl hexyl acrylate52578-826N2AV- \n / Amine -\nIV-27.5Step - 2 Product\nAcrylate 0.255-600.2 hr / dispersed wellAV-36.8/SAP-52.5/Amine-38.7/HV-76.2/IV-7.9
74-752.5yellowish liq. Traces of particlesIodine valueTime55-600.5 hr feed of phosphate ester
673.555-602.5 hr stirred well
285.5Tested for Violet-23 & Black
Both pigment resolubility fail
42i) Esteem BEP 1450 ( HV-40 LOD-3.1 %) Lot-2505013A\nR-2433200 gm400.2 Epomine SP- 01872.874-812FeedStep - 1 Product\nPhosphate 0.85
26.6.25ii) Phosphorous pentaoxide5.9 gm70-751Brownish crystal2 ethyl hexyl acrylate169.178-826N2AV- \n / Amine -\nIV-27.5Step - 2 Product\nAcrylate 0.1555-600.2 hr / dispersed wellAV-32.6/ SAP-64/Amine-40.5/IV-6.2
74-753AV-36.85Iodine valueTime55-600.5 hr feed of phosphate ester
55355-602.5 hr stirred well turbidity found
27.55.5Non uniform mass
Mono-15.5/ Di-72/Free A-0.53
48i) Vicaspin LUB 1010 (R225100845) Bu- EO-PO\nHV-62.3/ MW-900178450.2i) Epomine SP- 018300.280Step - 1 Product\nPhosphate ester0.85P-1.82%
20.10.25ii) Phosphorous pentaoxide9.357753.5Clear mass no particlesAV-52.52ii) 2 ethyl hexyl acrylate70279-81Feed of RM-IIStep - 2 Product \nAcrylate 0.150.5Heating acrylate intermediate \n@ 55 deg C
P-2.14%Mono-24.44 / Di- 51.76/ Free acid-0.240.5Feed of phosphate ester
5.579-81IV-26.1 @ 5.5 hrs3.5Stirrer well , clear \ntransparent massAV-44.36/ HV-46.58/SAP-62.14\n/Amine-36.25/ IV-5.8
Yellowish clear \ntransparent massTested over pigment Black, Blue, Violet-23/27 etc\nAll having matching resolubility while reduced gloss in violet
RM from above Batch
LBN-48 (Q)i) Acrylate 0.15
ii) Dimethyl sulphate0.00565-751 hrClear transparent mass
iii) Phosphate 0.8555-602.5 hrYellowish transparent \nclear mass
AV-52/Amine-31.67\n/IV-3.48/SAP-84.9/HV-38.6Tested on Violet 23\n resolubility ok
49i) Vicaspin LUB 1010 (R225100845) Bu- EO-PO\nHV-62.3/ MW-900208450.2i) Epomine SP- 018300.280Step - 1 Product\nPhosphate ester0.87P-1.86 %AV-46.5/ HV-49.4/SAP-61.98\n/Amine-20.2/ IV-2.58
1.11.2025ii) Phosphorous pentaoxide10.93753.5Clear mass no particles AV-51.87ii) 2 ethyl hexyl acrylate70279-81Feed of RM-IIStep - 2 Product \nAcrylate0.130.5Heating acrylate intermediate \n@ 55 deg CTested over pigment Black, Blue, Violet-23/27 etc\nAll having matching resolubility in black, blue & viloet 27 while slight reduced in gloss found in all pigments
P-2.14%Mono-22.56 / Di- 48.93/ Free acid-1.0960.5Feed of phosphate ester
5.579-81IV-26.1 @ 5.5 hrs3.5Stirrer well , clear \ntransparent mass
50i) Vicaspin LUB 1010 (R225100845) Bu- EO-PO\nHV-62.3/ MW-900301450.2Clear mass no particlesi) Epomine SP- 018300.280B.No- 50B\nStep - 1 Product\nPhosphate ester0.8P-1.71 %AV-44.14/Amine-47.1/ IV-4.9/ \nSAP-84.29/HV-58.5
5.11.25ii) Phosphorous pentaoxide15.82753.5AV-52.5ii) 2 ethyl hexyl acrylate70279-81Feed of RM-IIStep - 2 Product \nAcrylate0.20.5Heating acrylate intermediate \n@ 55 deg CTested on Black & violet pigment \nResolubility less while other parameters nearby
Mono-23.5 / Di- 53.2/ Free acid-0.10.5Feed of phosphate ester
P-2.14%5.579-81IV-26.1 @ 5.5 hrs3.5Stirrer well , clear \ntransparent mass
Yellowish clear \ntransparent mass
B.No-50 Ai) Acrylate (15%) 37.5 65-700.2
ii) DMS (1%) 2.52Feed over 15 min
70-751.5 hr clear yellowish\n mass
iii) Phosphate ester- (85%) 212.555-620.5 hr feed of RM-III)
58-623 hr/ Clear uniform mass\nSlight turbidity
AV-48.7/amine-31.08 /IV-4.58\n/SAP-88.4/HV-45.5Tested on Black & violet pigment \nResolubility less while other parameters nearby

Extracted values

checked
Cited: sheet 9076_Experiments, batch block '40', csv rows 354-361 (highlighted). Compare with the original on the left. Press Enter to OK the highlighted value, or click OK / fix on any value. Experiment: exp-9076-040

Process steps

StepCharged What happenedResults
Step 1
temperature 40; 70-75 time_h 0.2 h; 3.5 h
remarks: {'type': 'note', 'text': "Step 1 'Other' column holds prose, not results: 'RBF with SP-18', 'AIBN 0.6 gm added', 'Started feed 2 EH acrylate'. Carried as procedure events, not dropped."}; {'type': 'note', 'text': "Material 1 name cell reads 'R-1400 R-188 (1000)'; the '(1000)' suffix is part of the name cell, not a separate quantity."}
R-1400 R-188 · 157
role reactant · verbatim R-1400 R-188 (1000)
PPA · 5.74
role reactant · verbatim PPA ( 106 %)
#TimeTempAtmWhat happened
1 0.2 40
type temperature · verbatim 40 / 0.2
2 3.5 70-75
type temperature · verbatim 70-75 / 3.5
3
type condition · verbatim RBF with SP-18
4 10 min 79 deg C
AIBN 0.6 gm added
type addition · verbatim AIBN 0.6 gm added ,79 deg C,10 min stirrerd
5 2 hr 79-81
Started feed 2 EH acrylate
type feed · verbatim Started feed 2 EH acrylate,79-81,2 hr
Step 2
temperature 78-82 time_h 3.5 h; 5.5 h
2 ethyl hexyl acrylate · 210
role reactant · verbatim ii) 2 ethyl hexyl acrylate
AIBN · 0.6 gm
role reactant · verbatim iii) AIBN
#TimeTempAtmWhat happened
1 3.5 78-82
type temperature · verbatim 78-82 / 3.5
2 5.5 78-82
type temperature · verbatim 78-82 / 5.5
iodine_value 42
verbatim IV- 42
iodine_value 27.5
verbatim IV- 27.5
acid_value 44.3
note polysemous 'A.V.' cell of Step 2 (also carries Step 1 acid value by elimination) · verbatim AV-44.3
Step 3
temperature 55-60 time_h 25-30 min (feed of Step-I)
remarks: {'type': 'note', 'text': "Step 3 material reads 'Step - 2 Product' with Qty '20 gm' and a feed event 'feeding of Step-I over 25-30 min'. The named material (Step-2 product) and the feed source (Step-I) do not agree; copied verbatim as printed."}; {'type': 'note', 'text': 'Step 3 A.V. column is a multi-value result string (AV/SAP/HV/Amine/IV); all values emitted as measurements.'}
Step - 2 Product · 20 gm
role intermediate · verbatim Step - 2 Product
#TimeTempAtmWhat happened
1 55-60
feeding of Step-I over 25-30 min
type temperature · verbatim 55-60,feeding of Step-I over 25-30 min
acid_value 1.5
verbatim AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5
saponification_value 204
verbatim AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5
hv 183
verbatim AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5
amine_value 285
verbatim AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5
iodine_value 27.5
verbatim AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5
More actions — correct a value · link · ignore
Action Field path Corrected value Cause Note permanent — survives every re-run
History (1)
ActionFieldValueDate
verify 2026-08-20
Raw fragment JSON
{
  "fragment_id": "expt-block--40",
  "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
  "derived_from": "ocr/28112025  9076 Expt Table 2025.converted/28112025  9076 Expt Table 2025.converted_sheet_9076_Experiments.csv",
  "locator": "sheet 9076_Experiments, batch block '40', csv rows 354-361",
  "extractor": "qwen-tasks/extract-expt-block.md",
  "target_aliases": [
    "40"
  ],
  "document_role": "summary_table",
  "payload": {
    "record_type": "synthesis",
    "process_steps": [
      {
        "step": 1,
        "materials": [
          {
            "name": "R-1400  R-188",
            "qty_g": "157",
            "role": "reactant",
            "verbatim": "R-1400  R-188  (1000)"
          },
          {
            "name": "PPA",
            "qty_g": "5.74",
            "role": "reactant",
            "verbatim": "PPA ( 106 %)"
          }
        ],
        "procedure": [
          {
            "seq": 1,
            "type": "temperature",
            "temperature": "40",
            "time_h": "0.2",
            "verbatim": "40 / 0.2"
          },
          {
            "seq": 2,
            "type": "temperature",
            "temperature": "70-75",
            "time_h": "3.5",
            "verbatim": "70-75 / 3.5"
          },
          {
            "seq": 3,
            "type": "condition",
            "verbatim": "RBF with SP-18"
          },
          {
            "seq": 4,
            "type": "addition",
            "temperature": "79 deg C",
            "time_h": "10 min",
            "event": "AIBN  0.6 gm added",
            "verbatim": "AIBN  0.6 gm added ,79 deg C,10 min stirrerd"
          },
          {
            "seq": 5,
            "type": "feed",
            "temperature": "79-81",
            "time_h": "2 hr",
            "event": "Started feed 2 EH acrylate",
            "verbatim": "Started feed 2 EH acrylate,79-81,2 hr"
          }
        ],
        "conditions": {
          "temperature": "40; 70-75",
          "time_h": "0.2 h; 3.5 h"
        },
        "results": [],
        "remarks": "{'type': 'note', 'text': \"Step 1 'Other' column holds prose, not results: 'RBF with SP-18', 'AIBN 0.6 gm added', 'Started feed 2 EH acrylate'. Carried as procedure events, not dropped.\"}; {'type': 'note', 'text': \"Material 1 name cell reads 'R-1400  R-188  (1000)'; the '(1000)' suffix is part of the name cell, not a separate quantity.\"}"
      },
      {
        "step": 2,
        "materials": [
          {
            "name": "2 ethyl hexyl acrylate",
            "qty_g": "210",
            "role": "reactant",
            "verbatim": "ii)   2 ethyl hexyl acrylate"
          },
          {
            "name": "AIBN",
            "qty_g": "0.6 gm",
            "role": "reactant",
            "verbatim": "iii) AIBN"
          }
        ],
        "procedure": [
          {
            "seq": 1,
            "type": "temperature",
            "temperature": "78-82",
            "time_h": "3.5",
            "verbatim": "78-82 / 3.5"
          },
          {
            "seq": 2,
            "type": "temperature",
            "temperature": "78-82",
            "time_h": "5.5",
            "verbatim": "78-82 / 5.5"
          }
        ],
        "conditions": {
          "temperature": "78-82",
          "time_h": "3.5 h; 5.5 h"
        },
        "results": [
          {
            "parameter": "iodine_value",
            "value": "42",
            "verbatim": "IV- 42"
          },
          {
            "parameter": "iodine_value",
            "value": "27.5",
            "verbatim": "IV- 27.5"
          },
          {
            "parameter": "acid_value",
            "value": "44.3",
            "note": "polysemous 'A.V.' cell of Step 2 (also carries Step 1 acid value by elimination)",
            "verbatim": "AV-44.3"
          }
        ],
        "remarks": ""
      },
      {
        "step": 3,
        "materials": [
          {
            "name": "Step - 2 Product",
            "qty_g": "20 gm",
            "role": "intermediate",
            "verbatim": "Step -  2 Product"
          }
        ],
        "procedure": [
          {
            "seq": 1,
            "type": "temperature",
            "temperature": "55-60",
            "event": "feeding of Step-I over 25-30 min",
            "verbatim": "55-60,feeding of Step-I over 25-30 min"
          }
        ],
        "conditions": {
          "temperature": "55-60",
          "time_h": "25-30 min (feed of Step-I)"
        },
        "results": [
          {
            "parameter": "acid_value",
            "value": "1.5",
            "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
          },
          {
            "parameter": "saponification_value",
            "value": "204",
            "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
          },
          {
            "parameter": "hv",
            "value": "183",
            "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
          },
          {
            "parameter": "amine_value",
            "value": "285",
            "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
          },
          {
            "parameter": "iodine_value",
            "value": "27.5",
            "verbatim": "AV-1.5/SAP-204/\nHV-183/Amine-285/IV-27.5"
          }
        ],
        "remarks": "{'type': 'note', 'text': \"Step 3 material reads 'Step -  2 Product' with Qty '20 gm' and a feed event 'feeding of Step-I over 25-30 min'. The named material (Step-2 product) and the feed source (Step-I) do not agree; copied verbatim as printed.\"}; {'type': 'note', 'text': 'Step 3 A.V. column is a multi-value result string (AV/SAP/HV/Amine/IV); all values emitted as measurements.'}"
      }
    ],
    "observations": []
  },
  "notes": "Batch block '40'. Step 1 (epoxidation, RBF with SP-18, AIBN, 2-EH-acrylate feed) has a 2-stage temp/time ramp (40/0.2, 70-75/3.5) plus prose in the 'Other' column carried as procedure events. Step 2 (2 ethyl hexyl acrylate + AIBN) has a 78-82 ramp over 3.5 h and 5.5 h with iodine values IV-42 and IV-27.5. Step 3 charges 'Step -  2 Product' (20 gm) at 55-60 with a feed of Step-I over 25-30 min, and the final product analysis cell 'AV-1.5/SAP-204/HV-183/Amine-285/IV-27.5'. The polysemous Step 2 'A.V.' cell holds 'AV-44.3' (acid value). The printed Remarks column (rightmost) is empty for this block; no date marker line printed. All values copied verbatim; no conversions made.",
  "field_confidence": {}
}