Observations
Expt Table remarks: 55 Stirre well (N-2); 30 min 55 Feed of Phosphate (N-2); 10 min 55 Turbidity found (N-2); 30 min 55 Turbidity reduced (N-2); 30 min 58 Turbidity reduced (N-2); 30 57-59 Found foam in reaction mass (N-2); 1.5 hr 57-59 Found foam at top of mass; Cool to RT
Raw materials (collected from the per-step charges)
| Step | Material | Role |
|---|---|---|
| 1 | Surfol R-1400 / MW 1500 | reactant |
| 1 | PolyPhosphoric acid | reactant |
| 1 | Phosphorous pentaoxide | reactant |
| 2 | Epomine SP- 018 | reactant |
| 2 | 2 ethyl hexyl acrylate | reactant |
| 2 | AIBN | catalyst |
| 3 | Step - 1 Product | intermediate |
| 3 | Step - 2 Product | intermediate |
Process
| Step | Conditions | Charged | What happened | Results |
|---|---|---|---|---|
|
Step 1
28112025 9076 Expt Table 2025.xls
|
temperature: 54 / 56 / 68 / 55 (PPA feed) / 77 / 55 (P2O5 feed) / 75-78 / 82-85time_h: 0.5 / 2.5 / 2 / 0.1 (10 min) / 2.5 / 0.1 (10 min) / 2.5 / 1.5 hr |
Surfol R-1400 / MW 1500 PolyPhosphoric acid Phosphorous pentaoxide
|
Step 1 A.V. column cell 'AV-35.5' (independent of end-cell AV-35.6)
—
|
acid_value 35.6 saponification_value 39.5 hv 37.6 |
|
Step 2
28112025 9076 Expt Table 2025.xls
|
temperature: 79 / 79 (AIBN) / 79-81 (feed) / 78-82 / 78-82time_h: 10 min / 2 hr (feed) / 3.5 / 5.5 |
Epomine SP- 018 2 ethyl hexyl acrylate AIBN
|
RBF with SP-18 (RBF = round-bottom flask)
—
|
iodine_value 42 iodine_value 27.5 |
|
Step 3
28112025 9076 Expt Table 2025.xls
|
temperature: 55 / 55 / 55 / 55 / 58 / 57-59 / 57-59 / RTatmosphere: N-2time_h: (stir) / 30 min / 10 min / 30 min / 30 min / 30 / 1.5 hr |
Step - 1 Product Step - 2 Product
|
Step 3 A.V. column cell 'AV-35.5' (independent of the two final result cells)
—
|
acid_value 1.5 saponification_value 204 hv 183 amine_value 285 iodine_value 27.5 acid_value 29.67 saponification_value 71.87 hv 44.67 amine_value 46.5 iodine_value 9.4 |
Sample S 9076 #39
result
Violet 23 (NC-PU ink)
| Parameter | This sample | Standard (BYK 9076 Standard) |
|---|---|---|
| Viscosity | 40 sec | 35 sec |
| Gloss | 61 | 65.5 |
| Colour Strength | 96 - 97% | 1 |
| Resolubility | 2 | 4 |
| Transparency | Eq. to Std | Ref as Std |
APP DATA- BYK 9076 equivalent.xlsx
result
Violet 27 (NC-PU ink)
| Parameter | This sample | Standard (BYK 9076 Standard) |
|---|---|---|
| Viscosity | 40 sec | 37 sec |
| Gloss | 7 | 6.8 |
| Colour Strength | 1 | 1 |
| Resolubility | 4 | 4 |
| Transparency | Eq. to Std | Ref as Std |
APP DATA- BYK 9076 equivalent.xlsx
Where this record comes from
APP DATA- BYK 9076 equivalent.xlsx
— application testing
28112025 9076 Expt Table 2025.xls
— researcher summary (cross-check)
Something wrong on this page? Record a correction
Your correction is permanent: it survives every re-extraction and the field can no longer be changed by the system.
Field-by-field provenance (6 fields) — for auditors
2 extraction fragments · merged 2026-08-25 · 0 human-validated fields
Fix a wrong or missing extraction side-by-side with the original:
app-data--S 9076 #39
expt-block--39
| Field | Source | Extractor | Conf. |
|---|---|---|---|
| samples[0] | APP DATA- BYK 9076 equivalent.xlsx sheet BYK_9076_equivalent, rows 78-78 | parse_app_data.py@unversioned | high |
| record_type | 28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task) | qwen-tasks/extract-expt-block.md@unversioned | high |
| process_steps[0] | 28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task) | qwen-tasks/extract-expt-block.md@unversioned | high |
| process_steps[1] | 28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task) | qwen-tasks/extract-expt-block.md@unversioned | high |
| process_steps[2] | 28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task) | qwen-tasks/extract-expt-block.md@unversioned | high |
| observations | 28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task) | qwen-tasks/extract-expt-block.md@unversioned | high |
Raw record JSON
{
"record_id": "exp-9076-039",
"project": "9076",
"aliases": [
"S 9076 #39",
"39"
],
"provenance": {
"fragments": [
"app-data--S 9076 #39",
"expt-block--39"
],
"field_provenance": {
"samples[0]": {
"source_file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx",
"extractor": "parse_app_data.py",
"extractor_version": "unversioned",
"extracted_date": "2026-08-19",
"locator": "sheet BYK_9076_equivalent, rows 78-78",
"human_checked": true
},
"record_type": {
"source_file": "docs/Project Expt Report/28112025 9076 Expt Table 2025.xls",
"extractor": "qwen-tasks/extract-expt-block.md",
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"extracted_date": "",
"locator": "sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task)",
"human_checked": true
},
"process_steps[0]": {
"source_file": "docs/Project Expt Report/28112025 9076 Expt Table 2025.xls",
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"extracted_date": "",
"locator": "sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task)",
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},
"process_steps[1]": {
"source_file": "docs/Project Expt Report/28112025 9076 Expt Table 2025.xls",
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"locator": "sheet 9076_Experiments, batch block '39' (slicer row span not available - block provided verbatim in task)",
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},
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},
"observations": {
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}
},
"last_merged": "2026-08-25"
},
"documents": [
{
"file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx",
"role": "application_test",
"link_basis": "alias match: S 9076 #39",
"link_status": "rule"
},
{
"file": "docs/Project Expt Report/28112025 9076 Expt Table 2025.xls",
"role": "summary_table",
"link_basis": "alias match: 39",
"link_status": "rule"
}
],
"validation": {
"validated_fields": {},
"corrections_applied": []
},
"samples": [
{
"sample_id": "S 9076 #39",
"application_tests": [
{
"test": "Violet 23",
"system": "NC-PU ink",
"conditions": "trial 16.01.2025",
"result": "Viscosity: 40 sec; Gloss: 61; Colour Strength: 96 - 97%; Resolubility: 2; Transparency: Eq. to Std",
"vs_reference": "BYK 9076 Standard — Viscosity: 35 sec; Gloss: 65.5; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
"file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
},
{
"test": "Violet 27",
"system": "NC-PU ink",
"conditions": "trial 16.01.2025",
"result": "Viscosity: 40 sec; Gloss: 7; Colour Strength: 1; Resolubility: 4; Transparency: Eq. to Std",
"vs_reference": "BYK 9076 Standard — Viscosity: 37 sec; Gloss: 6.8; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
"file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
}
]
}
],
"record_type": "synthesis",
"process_steps": [
{
"step": 1,
"materials": [
{
"name": "Surfol R-1400 / MW 1500",
"qty_g": "265",
"role": "reactant",
"verbatim": "i) Surfol R-1400 / MW 1500 ( 2 kg) \\nR-188, 265"
},
{
"name": "PolyPhosphoric acid",
"qty_g": "4.67",
"role": "reactant",
"verbatim": "ii) PolyPhosphoric acid (106%), 4.67"
},
{
"name": "Phosphorous pentaoxide",
"qty_g": "3.65",
"role": "reactant",
"verbatim": "ii) Phosphorous pentaoxide, 3.65"
}
],
"procedure": [
{
"seq": 1,
"temperature": "54",
"time_h": "0.5",
"verbatim": "54 / 0.5"
},
{
"seq": 2,
"temperature": "56",
"time_h": "2.5",
"verbatim": "56 / 2.5"
},
{
"seq": 3,
"temperature": "68",
"time_h": "2",
"verbatim": "68 / 2"
},
{
"seq": 4,
"temperature": "55 deg",
"time_h": "0.1",
"action": "PPA feed at 55 deg C for 10 min",
"verbatim": "PPA feed at 55 deg C for 10 min / 55 / 0.1"
},
{
"seq": 5,
"temperature": "77",
"time_h": "2.5",
"action": "(PPA feed continued / hold)",
"verbatim": "77 / 2.5"
},
{
"seq": 6,
"temperature": "55 deg",
"time_h": "0.1",
"action": "P2O5 feed at 55 deg C for 10 min",
"verbatim": "P2O5 feed at 55 deg C for 10 min / 55 / 0.1"
},
{
"seq": 7,
"temperature": "75-78",
"time_h": "2.5",
"verbatim": "75-78 / 2.5"
},
{
"seq": 8,
"temperature": "82-85",
"time_h": "1.5 hr",
"action": "After ward heated on heating mantle",
"verbatim": "After ward heated on heating mantle / 82-85 / 1.5 hr"
}
],
"conditions": {
"temperature": "54 / 56 / 68 / 55 (PPA feed) / 77 / 55 (P2O5 feed) / 75-78 / 82-85",
"time_h": "0.5 / 2.5 / 2 / 0.1 (10 min) / 2.5 / 0.1 (10 min) / 2.5 / 1.5 hr"
},
"results": [
{
"parameter": "acid_value",
"value": "35.6",
"verbatim": "AV-35.6/ SAP39.5/ HV-37.6"
},
{
"parameter": "saponification_value",
"value": "39.5",
"verbatim": "AV-35.6/ SAP39.5/ HV-37.6"
},
{
"parameter": "hv",
"value": "37.6",
"verbatim": "AV-35.6/ SAP39.5/ HV-37.6"
}
],
"remarks": "Step 1 A.V. column cell 'AV-35.5' (independent of end-cell AV-35.6)"
},
{
"step": 2,
"materials": [
{
"name": "Epomine SP- 018",
"qty_g": "90",
"role": "reactant",
"verbatim": "i) Epomine SP- 018, 90"
},
{
"name": "2 ethyl hexyl acrylate",
"qty_g": "210",
"role": "reactant",
"addition": "feed",
"verbatim": "ii) 2 ethyl hexyl acrylate, 210"
},
{
"name": "AIBN",
"qty_g": "0.6",
"unit": "gm",
"role": "catalyst",
"verbatim": "iii) AIBN, 0.6 gm"
}
],
"procedure": [
{
"seq": 1,
"action": "RBF with SP-18",
"verbatim": "RBF with SP-18"
},
{
"seq": 2,
"temperature": "79",
"action": "(initial hold)",
"verbatim": "79"
},
{
"seq": 3,
"temperature": "79 deg C",
"time_h": "10 min",
"action": "AIBN 0.6 gm added",
"verbatim": "AIBN 0.6 gm added , 79 deg C, 10 min stirrerd"
},
{
"seq": 4,
"action": "Started feed 2 EH acrylate",
"verbatim": "Started feed 2 EH acrylate"
},
{
"seq": 5,
"temperature": "79-81",
"time_h": "2 hr",
"action": "(feed 2 EH acrylate)",
"verbatim": "79-81 / 2 hr"
},
{
"seq": 6,
"temperature": "78-82",
"time_h": "3.5",
"verbatim": "78-82 / 3.5"
},
{
"seq": 7,
"temperature": "78-82",
"time_h": "5.5",
"verbatim": "78-82 / 5.5"
}
],
"conditions": {
"temperature": "79 / 79 (AIBN) / 79-81 (feed) / 78-82 / 78-82",
"time_h": "10 min / 2 hr (feed) / 3.5 / 5.5"
},
"results": [
{
"parameter": "iodine_value",
"value": "42",
"verbatim": "IV- 42"
},
{
"parameter": "iodine_value",
"value": "27.5",
"verbatim": "IV- 27.5"
}
],
"remarks": "RBF with SP-18 (RBF = round-bottom flask)"
},
{
"step": 3,
"materials": [
{
"name": "Step - 1 Product",
"qty_g": "240",
"role": "intermediate",
"verbatim": "Step - 1 Product, 240"
},
{
"name": "Step - 2 Product",
"qty_g": "60",
"role": "intermediate",
"verbatim": "Step - 2 Product , 60"
}
],
"procedure": [
{
"seq": 1,
"temperature": "55",
"action": "Stirre well",
"atmosphere": "N-2",
"verbatim": "55, Stirre well, N-2"
},
{
"seq": 2,
"temperature": "55",
"time_h": "30 min",
"action": "Feed of Phosphate",
"atmosphere": "N-2",
"verbatim": "30 min, 55, Feed of Phosphate, N-2"
},
{
"seq": 3,
"temperature": "55",
"time_h": "10 min",
"observation": "Turbidity found",
"atmosphere": "N-2",
"verbatim": "10 min , 55, Turbidity found, N-2"
},
{
"seq": 4,
"temperature": "55",
"time_h": "30 min",
"observation": "Turbidity reduced",
"atmosphere": "N-2",
"verbatim": "30 min, 55, Turbidity reduced , N-2"
},
{
"seq": 5,
"temperature": "58",
"time_h": "30 min",
"observation": "Turbidity reduced",
"atmosphere": "N-2",
"verbatim": "30 min, 58, Turbidity reduced , N-2"
},
{
"seq": 6,
"temperature": "57-59",
"time_h": "30",
"observation": "Found foam in\\n reaction mass",
"atmosphere": "N-2",
"verbatim": "30, 57-59, Found foam in\\n reaction mass, N-2"
},
{
"seq": 7,
"temperature": "57-59",
"time_h": "1.5 hr",
"observation": "Found foam at\\n top of mass",
"verbatim": "1.5 hr, 57-59, Found foam at\\n top of mass"
},
{
"seq": 8,
"temperature": "RT",
"action": "Cool to RT",
"verbatim": "Cool to RT"
}
],
"conditions": {
"temperature": "55 / 55 / 55 / 55 / 58 / 57-59 / 57-59 / RT",
"atmosphere": "N-2",
"time_h": "(stir) / 30 min / 10 min / 30 min / 30 min / 30 / 1.5 hr"
},
"results": [
{
"parameter": "acid_value",
"value": "1.5",
"verbatim": "AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5"
},
{
"parameter": "saponification_value",
"value": "204",
"verbatim": "AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5"
},
{
"parameter": "hv",
"value": "183",
"verbatim": "AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5"
},
{
"parameter": "amine_value",
"value": "285",
"verbatim": "AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5"
},
{
"parameter": "iodine_value",
"value": "27.5",
"verbatim": "AV-1.5/SAP-204/ HV-183/Amine-285/IV-27.5"
},
{
"parameter": "acid_value",
"value": "29.67",
"verbatim": "AV-29.67/SAP-71.87/ HV-44.67/Amine-46.5/ IV-9.4"
},
{
"parameter": "saponification_value",
"value": "71.87",
"verbatim": "AV-29.67/SAP-71.87/ HV-44.67/Amine-46.5/ IV-9.4"
},
{
"parameter": "hv",
"value": "44.67",
"verbatim": "AV-29.67/SAP-71.87/ HV-44.67/Amine-46.5/ IV-9.4"
},
{
"parameter": "amine_value",
"value": "46.5",
"verbatim": "AV-29.67/SAP-71.87/ HV-44.67/Amine-46.5/ IV-9.4"
},
{
"parameter": "iodine_value",
"value": "9.4",
"verbatim": "AV-29.67/SAP-71.87/ HV-44.67/Amine-46.5/ IV-9.4"
}
],
"remarks": "Step 3 A.V. column cell 'AV-35.5' (independent of the two final result cells)"
}
],
"observations": "Expt Table remarks: 55 Stirre well (N-2); 30 min 55 Feed of Phosphate (N-2); 10 min 55 Turbidity found (N-2); 30 min 55 Turbidity reduced (N-2); 30 min 58 Turbidity reduced (N-2); 30 57-59 Found foam in reaction mass (N-2); 1.5 hr 57-59 Found foam at top of mass; Cool to RT"
}