{
  "record_id": "exp-9076-056",
  "project": "9076",
  "aliases": [
    "S 9076 #56",
    "Batch - 56",
    "ByK 9076"
  ],
  "provenance": {
    "fragments": [
      "app-data--S 9076 #56",
      "qwen-extract--9076-exp-48-60-1--batch-56",
      "qwen-extract--9076-exp-48-60_1--batch-56"
    ],
    "field_provenance": {
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        "extractor": "parse_app_data.py",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-19",
        "locator": "sheet BYK_9076_equivalent, rows 14-14",
        "human_checked": true
      },
      "date": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
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      "aim": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
      },
      "conditions.atmosphere": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
      },
      "materials[0]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
      },
      "materials[1]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
      },
      "materials[2]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
      },
      "materials[3]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
      },
      "procedure_summary": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "direct-v1",
        "extracted_date": "2026-08-25",
        "locator": "Page 19-20",
        "human_checked": true
      },
      "observations": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "human_checked": true
      },
      "materials[4]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "materials[5]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "materials[6]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "materials[7]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "materials[8]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "process_steps[0]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "process_steps[1]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "process_steps[2]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "confidence": "medium",
        "human_checked": true
      },
      "samples[1]": {
        "source_file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
        "extractor": "qwen-tasks/extract-fragment.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "pages 17-18",
        "human_checked": true
      }
    },
    "last_merged": "2026-08-25"
  },
  "documents": [
    {
      "file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx",
      "role": "application_test",
      "link_basis": "alias match: S 9076 #56",
      "link_status": "rule"
    },
    {
      "file": "pdf/9076 Data for Raven POC project/Handwritten  notes/9076 Exp 48-60_1.pdf",
      "role": "handwritten_notes",
      "link_basis": "alias match: Batch - 56",
      "link_status": "rule"
    }
  ],
  "validation": {
    "validated_fields": {},
    "corrections_applied": []
  },
  "samples": [
    {
      "sample_id": "S 9076 #56",
      "application_tests": [
        {
          "test": "Violet 23",
          "system": "NC-PU ink",
          "conditions": "trial 29.01.2026",
          "result": "Viscosity: 40 sec; Gloss: 61.5; Colour Strength: 93 - 94.00%; Resolubility: 4; Transparency: Opaque",
          "vs_reference": "BYK 9076 Standard — Viscosity: 32 sec; Gloss: 67.3; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
          "file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
        },
        {
          "test": "Violet 27",
          "system": "NC-PU ink",
          "conditions": "trial 29.01.2026",
          "result": "Viscosity: 35 sec; Gloss: 6.8; Colour Strength: 95 - 96.00%; Resolubility: 4; Transparency: Opaque",
          "vs_reference": "BYK 9076 Standard — Viscosity: 33 sec; Gloss: 8; Colour Strength: 1; Resolubility: 4; Transparency: Ref as Std",
          "file": "docs/Application data Summary/APP DATA- BYK 9076 equivalent.xlsx"
        }
      ]
    },
    {
      "id": "Batch - 56",
      "analytical": [
        {
          "verbatim": "AV - 23.85"
        },
        {
          "verbatim": "MONO - 500 (crossed out)"
        },
        {
          "verbatim": "Diester - 32"
        },
        {
          "verbatim": "Free Acid - 0.0"
        },
        {
          "verbatim": "HV - 27.5 / 5.5"
        },
        {
          "verbatim": "AV - 15.9"
        },
        {
          "verbatim": "Amine - 33.8"
        }
      ],
      "sample_id": "unspecified sample"
    }
  ],
  "date": "20/1/26",
  "aim": "Handwritten lab-note for a BYK 9076 analogue batch (9076 Exp 48-60 series): Step-I phosphate ester of the polyol with P2O5, Step-II acylate/acrylate intermediate from SP-18 (or Lupasol G-20) with 2-ethyl hexyl acrylate/acylate, Step-III neutralisation of the phosphate ester with the acylate intermediate.",
  "conditions": {
    "atmosphere": "N2",
    "other": "Step I: RT-50 to 75-81°C; Step II: 75-79 to 77-81°C; Step III: 55-59 to 55-58°C"
  },
  "materials": [
    {
      "name": "BEP - 1100M",
      "quantity": "200",
      "unit": "gm",
      "role": "reactant",
      "notes": "HV - 64.29"
    },
    {
      "name": "P2O5",
      "quantity": "4.511",
      "unit": "gm",
      "role": "reactant"
    },
    {
      "name": "Epoxinsp-18",
      "quantity": "72.8",
      "unit": "gm",
      "role": "reactant"
    },
    {
      "name": "2-Ethyl hexyl Acylate",
      "quantity": "169.1",
      "unit": "gm",
      "role": "reactant"
    },
    {
      "name": "BEP - 1100M, HV - 64.29",
      "quantity": "200",
      "unit": "gm",
      "molecular_weight": "872",
      "moles": "0.229",
      "role": "reactant"
    },
    {
      "name": "P2O5",
      "quantity": "4.511",
      "unit": "gm",
      "molecular_weight": "141.94",
      "moles": "0.0317",
      "role": "reactant"
    },
    {
      "name": "2-Ethyl hexyl Acylate",
      "quantity": "169.1",
      "unit": "gm",
      "molecular_weight": "184.27",
      "role": "reactant"
    },
    {
      "name": "Phosphate Ester (Step - I)",
      "quantity": "85",
      "unit": "gm",
      "percentage": "85%",
      "role": "reactant"
    },
    {
      "name": "Acylate Intermediate (Step - II)",
      "quantity": "15",
      "unit": "gm",
      "percentage": "15%",
      "role": "reactant"
    }
  ],
  "procedure_summary": "Step I: Phosphate ester synthesis using BEP-1100M. Step II: Acylate intermediate synthesis. Step III: Neutralization.",
  "observations": "Step I: Initially dispersion of P2O5, Trace of particles found, Yellowish tincture, AV - 23.85, Diester - 32, Free Acid - 0.0.\nStep II: HV - 27.5 / 5.5, Clear transparent Mass.\nStep III: Yellowish transparent mass, Clear mass, AV - 15.9, Amine - 33.8.\n\nCharged BEP-1100m - 200gm, Feed of P2O5 - 4.5 in 10min\nInitially dispersion of P2O5, Trace of particles found, Yellowish tincture. AV - 23.85 / MONO - 500 (crossed out), Diester - 32, Free Acid - 0.0\nCharged Sp-18 - 72.8\nFeed of 2-Ethyl hexyl Acylate over 2hrs.\nHV - 27.5 / 5.5, Clear transparent Mass\nCharged Acylate Intermediate - 15 gm, Heating to 55-58°C / Feed of Phosphate Ester 85 gm over 10 min.\nYellowish transparent mass.\nClear mass / AV - 15.9, Amine - 33.8",
  "process_steps": [
    {
      "name": "STEP-I Phosphate Ester",
      "process": [
        {
          "time": "0.5",
          "temperature": "RT-50/N2",
          "observation": "Charged BEP-1100m - 200gm, Feed of P2O5 - 4.5 in 10min"
        },
        {
          "time": "4.5",
          "temperature": "75-81/N2",
          "observation": "Initially dispersion of P2O5, Trace of particles found, Yellowish tincture. AV - 23.85 / MONO - 500 (crossed out), Diester - 32, Free Acid - 0.0"
        }
      ],
      "measurements": [
        {
          "verbatim": "AV - 23.85"
        },
        {
          "verbatim": "MONO - 500 (crossed out)"
        },
        {
          "verbatim": "Diester - 32"
        },
        {
          "verbatim": "Free Acid - 0.0"
        }
      ],
      "step": 1
    },
    {
      "name": "Step-II Acylate Intermediate",
      "process": [
        {
          "time": "0.5",
          "temperature": "75-79/N2",
          "observation": "Charged Sp-18 - 72.8"
        },
        {
          "time": "2 hrs",
          "temperature": "77/81 - N2",
          "observation": "Feed of 2-Ethyl hexyl Acylate over 2hrs."
        },
        {
          "time": "5.5",
          "temperature": "77-81 N2",
          "observation": "HV - 27.5 / 5.5, Clear transparent Mass"
        }
      ],
      "measurements": [
        {
          "verbatim": "HV - 27.5 / 5.5"
        }
      ],
      "step": 2
    },
    {
      "name": "Step - III) Neutralisation -",
      "process": [
        {
          "time": "0.5",
          "temperature": "55-59 / N2",
          "observation": "Charged Acylate Intermediate - 15 gm, Heating to 55-58°C / Feed of Phosphate Ester 85 gm over 10 min."
        },
        {
          "time": "2 hrs.",
          "temperature": "55-59 / N2",
          "observation": "Yellowish transparent mass."
        },
        {
          "time": "2-5 hrs.",
          "temperature": "55-58 / N2",
          "observation": "Clear mass / AV - 15.9, Amine - 33.8"
        }
      ],
      "measurements": [
        {
          "verbatim": "AV - 15.9"
        },
        {
          "verbatim": "Amine - 33.8"
        }
      ],
      "step": 3
    }
  ]
}