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Experiments / Batch 25 B

Batch 25 B no result yet

also written as 25-B
Observations

Expt Table remarks: After 2 hr feed slight turbidity /yellowish flowable liq Expt Table remarks: Vicasurf- 1010 Btaches (surfactant, no quantity printed) Expt Table remarks: Iodine value 350 (trailing I.V. reading, no time attached)

Raw materials (collected from the per-step charges)
StepMaterialQtyRole
1Sun Surfol R-1400- HV-56)147-
1PPA:P2O5 (30:70)1.578 gm :3.67gm-
1Vicasurf- 1010 Btaches-
2Epomine SP- 018150-
22 ethyl hexyl acrylate350-
3Step- 1 product80intermediate
3Step - 2 Product20intermediate
3AMP2-
Process
Step Conditions Charged What happened Results
Step 1
28112025 9076 Expt Table 2025.xls
temperature: 40 / 55-60time_h: 0.5 / 4.5atmosphere: N2
Sun Surfol R-1400- HV-56) 147
PPA:P2O5 (30:70) 1.578 gm :3.67gm
Vicasurf- 1010 Btaches
acid_value 41.2
Step 2
28112025 9076 Expt Table 2025.xls
temperature: 74-82 / 78-82time_h: 2 / 6 / 4 / 5atmosphere: N2
Epomine SP- 018 150
2 ethyl hexyl acrylate 350
acid_value 0.2 amine_value 255 iodine_value 34 iodine_value 38.5 iodine_value 34
Step 3
28112025 9076 Expt Table 2025.xls
temperature: 60time_h: 4atmosphere: N2
Step- 1 product 80
Step - 2 Product 20
AMP 2
After 2 hr feed slight turbidity /yellowish flowable liq
acid_value 36.86 amine_value 35.92 iodine_value 350

No test results linked to this batch yet.

Where this record comes from
28112025 9076 Expt Table 2025.xls — researcher summary (cross-check)
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Field-by-field provenance (4 fields) — for auditors
1 extraction fragments · merged 2026-08-25 · 0 human-validated fields
Fix a wrong or missing extraction side-by-side with the original: expt-block--25b
FieldSourceExtractorConf.
process_steps[0]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '25-B', csv rows 1-10 qwen-tasks/extract-expt-block.md@unversionedhigh
process_steps[1]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '25-B', csv rows 1-10 qwen-tasks/extract-expt-block.md@unversionedhigh
process_steps[2]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '25-B', csv rows 1-10 qwen-tasks/extract-expt-block.md@unversionedhigh
observations28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '25-B', csv rows 1-10 qwen-tasks/extract-expt-block.md@unversionedhigh
Raw record JSON
{
  "record_id": "exp-9076-025B",
  "project": "9076",
  "aliases": [
    "25-B"
  ],
  "provenance": {
    "fragments": [
      "expt-block--25b"
    ],
    "field_provenance": {
      "process_steps[0]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "sheet 9076_Experiments, batch block '25-B', csv rows 1-10",
        "human_checked": true
      },
      "process_steps[1]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "sheet 9076_Experiments, batch block '25-B', csv rows 1-10",
        "human_checked": true
      },
      "process_steps[2]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "sheet 9076_Experiments, batch block '25-B', csv rows 1-10",
        "human_checked": true
      },
      "observations": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "",
        "locator": "sheet 9076_Experiments, batch block '25-B', csv rows 1-10",
        "human_checked": true
      }
    },
    "last_merged": "2026-08-25"
  },
  "documents": [
    {
      "file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
      "role": "summary_table",
      "link_basis": "alias match: 25-B",
      "link_status": "rule"
    }
  ],
  "validation": {
    "validated_fields": {},
    "corrections_applied": []
  },
  "process_steps": [
    {
      "step": 1,
      "materials": [
        {
          "name": "Sun Surfol R-1400- HV-56)",
          "qty": "147",
          "role": "unknown",
          "note": "cell text 'Sun Surfol R-1400- HV-56)'; leading bracket of the trade name appears missing from the cell as printed",
          "verbatim": "Sun Surfol R-1400- HV-56)",
          "role_verbatim": "raw_material"
        },
        {
          "name": "PPA:P2O5 (30:70)",
          "qty": "1.578 \ngm :3.67gm",
          "role": "unknown",
          "note": "two-component charge kept verbatim as printed",
          "verbatim": "PPA:P2O5 (30:70),1.578 \ngm :3.67gm",
          "role_verbatim": "raw_material"
        },
        {
          "name": "Vicasurf- 1010 Btaches",
          "role": "unknown",
          "note": "named in the Remarks column at the end of the block, with no quantity; read as charged with Step 1 (emulsion step)",
          "verbatim": "Vicasurf- 1010 Btaches",
          "role_verbatim": "additive"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "temperature": "40",
          "time_h": "0.5",
          "verbatim": "40 / 0.5"
        },
        {
          "seq": 2,
          "temperature": "55-60",
          "time_h": "4.5",
          "atmosphere": "N2",
          "verbatim": "55-60 / 4.5 / N2"
        }
      ],
      "conditions": {
        "temperature": "40 / 55-60",
        "time_h": "0.5 / 4.5",
        "atmosphere": "N2"
      },
      "results": [
        {
          "parameter": "acid_value",
          "value": "41.2",
          "unit": "mg KOH/g",
          "note": "A.V. column of Step 1; interpreted as acid value from the 'A.V.' label (low-confidence interpretation)",
          "verbatim": "41.2"
        }
      ],
      "remarks": ""
    },
    {
      "step": 2,
      "materials": [
        {
          "name": "Epomine SP- 018",
          "qty": "150",
          "role": "unknown",
          "verbatim": "Epomine SP- 018,150",
          "role_verbatim": "raw_material"
        },
        {
          "name": "2 ethyl hexyl acrylate",
          "qty": "350",
          "role": "unknown",
          "note": "monomer charged at the start of the step; the Step 3 'Feed - 2 hr' feed note is read as the Step 2 feed time, not as a distinct reaction event",
          "verbatim": "2 ethyl hexyl acrylate,350",
          "role_verbatim": "raw_material"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "temperature": "74-82",
          "time_h": "2",
          "verbatim": "74-82 / 2"
        },
        {
          "seq": 2,
          "temperature": "78-82",
          "time_h": "6",
          "atmosphere": "N2",
          "feed": "Feed  - 2  hr",
          "note": "6 h stage at 78-82 oC N2; 'Feed - 2 hr' (printed in the Step 3 header row) read as the 2 h monomer feed within this stage",
          "verbatim": "78-82 / 6 / N2 / Feed  - 2  hr"
        },
        {
          "seq": 3,
          "temperature": "78-82",
          "time_h": "4",
          "note": "I.V. tracking stage 1 (Iodine value 38.5 at 4 h), from the block's trailing time/I.V. rows",
          "iv": "38.5",
          "verbatim": "4 / Iodine value 38.5"
        },
        {
          "seq": 4,
          "temperature": "78-82",
          "time_h": "5",
          "note": "I.V. tracking stage 2 (Iodine value 34 at 5 h), from the block's trailing time/I.V. rows",
          "iv": "34",
          "verbatim": "5 / Iodine value 34"
        }
      ],
      "conditions": {
        "temperature": "74-82 / 78-82",
        "time_h": "2 / 6 / 4 / 5",
        "atmosphere": "N2"
      },
      "results": [
        {
          "parameter": "acid_value",
          "value": "0.2",
          "unit": "mg KOH/g",
          "note": "first entry of the Step 2 A.V. cell 'AV- 0.2 / Amine -255 / IV-34'",
          "verbatim": "AV- 0.2"
        },
        {
          "parameter": "amine_value",
          "value": "255",
          "unit": "mg KOH/g",
          "note": "second entry of the Step 2 A.V. cell; sign of the printed '-255' read as a list separator per the column's mixed sign convention",
          "verbatim": "Amine -255"
        },
        {
          "parameter": "iodine_value",
          "value": "34",
          "note": "third entry of the Step 2 A.V. cell; matches the block's final I.V. reading",
          "verbatim": "IV-34"
        },
        {
          "parameter": "iodine_value",
          "value": "38.5",
          "time_h": "4",
          "note": "trailing time/I.V. row of the block, aligned positionally with the Step 2 columns",
          "verbatim": "Time 4 / Iodine value 38.5"
        },
        {
          "parameter": "iodine_value",
          "value": "34",
          "time_h": "5",
          "note": "trailing time/I.V. row of the block, aligned positionally with the Step 2 columns",
          "verbatim": "Time 5 / Iodine value 34"
        }
      ],
      "remarks": ""
    },
    {
      "step": 3,
      "materials": [
        {
          "name": "Step-  1 product",
          "qty": "80",
          "role": "intermediate",
          "note": "'Step-  1 product  (80)' as printed",
          "verbatim": "Step-  1 product  (80),80"
        },
        {
          "name": "Step -  2 Product",
          "qty": "20",
          "role": "intermediate",
          "note": "'Step -  2 Product  (20)' as printed",
          "verbatim": "Step -  2 Product  (20),20"
        },
        {
          "name": "AMP",
          "qty": "2",
          "role": "unknown",
          "note": "AMP added with the Step 2 product, from the material cell text",
          "verbatim": "2 gm AMP",
          "role_verbatim": "additive"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "temperature": "60",
          "time_h": "4",
          "atmosphere": "N2",
          "feed": "Feed  -  2  hr",
          "note": "feed event printed in the Step 3 temperature cell as printed; Step 2 product + AMP charged and fed in over 2 h at 60 oC N2 for a total of 4 h",
          "verbatim": "60 / 4 / N2 / Feed  -  2  hr"
        }
      ],
      "conditions": {
        "temperature": "60",
        "time_h": "4",
        "atmosphere": "N2"
      },
      "results": [
        {
          "parameter": "acid_value",
          "value": "36.86",
          "unit": "mg KOH/g",
          "note": "first entry of the Step 3 A.V. cell 'AV-36.86\nAmine-35.92'; interpretation of the label is low-confidence",
          "verbatim": "AV-36.86"
        },
        {
          "parameter": "amine_value",
          "value": "35.92",
          "unit": "mg KOH/g",
          "note": "second entry of the Step 3 A.V. cell; interpretation of the label is low-confidence",
          "verbatim": "Amine-35.92"
        },
        {
          "parameter": "iodine_value",
          "value": "350",
          "note": "I.V. printed in the Remarks column at the end of the block ('Vicasurf- 1010 Btaches...350'); no time attached, and the magnitude differs from the Step 2 I.V. readings (38.5, 34) — kept as printed, not force-fitted to Step 2",
          "verbatim": "350"
        }
      ],
      "remarks": "After 2 hr feed slight turbidity /yellowish flowable liq"
    }
  ],
  "observations": "Expt Table remarks: After 2 hr feed slight turbidity /yellowish flowable liq\nExpt Table remarks: Vicasurf- 1010 Btaches (surfactant, no quantity printed)\nExpt Table remarks: Iodine value 350 (trailing I.V. reading, no time attached)"
}