← Back batch 22 of 100 ← Batch 20 Batch 22 →
Experiments / Batch 21

Batch 21 no result yet

also written as 21 · LBN 21A · LBN 21B · LBN 21 C · LBN 21D · LBN 21E · LBN 21F
Observations

Expt Table remarks: Strength/gloss for C black good/ Resolubility issue

Raw materials (collected from the per-step charges)
StepMaterialGrade / notesQtyRM %Role
1Butanol EO - PO - 300 gm (Sunshield)HV-56300 greactant
1Phosphorous pentaoxide13.7 greactant
2Epomine SP- 01890 greactant
22 ethyl hexyl acrylate210 greactant
3Step- 1 product160 g80intermediate
3Step - 2 Product40 g20intermediate
Process
Step Conditions Charged What happened Results
Step 1
Step 1
28112025 9076 Expt Table 2025.xls
temperature: 40; then 65-75atmosphere: N2time_h: 1; then 4.5
Butanol EO - PO - 300 gm (Sunshield) 300g
Phosphorous pentaoxide 13.7g
A.V. 46.86
Step 2
Step 2
28112025 9076 Expt Table 2025.xls
temperature: 80-82; then 80-83atmosphere: N2time_h: 6; then 2
Epomine SP- 018 90g
2 ethyl hexyl acrylate 210g
iodine value 70 iodine value 37.2
Step 3
Step 3
28112025 9076 Expt Table 2025.xls
temperature: 60atmosphere: N2time_h: 605
Step- 1 product 160g
Step - 2 Product 40g
Sample LBN 21A — LBN 21 +3% AMP
Sample LBN 21B — LBN 21 +2% IPA
Sample LBN 21 C — LBN21 A + 2% mix xylene
Sample LBN 21D — LBN 21 +4% mix xylene
Sample LBN 21E — LBN 21D +1% MIBK
Sample LBN 21F — LBN 21 +2% ethyl cellosolve
Where this record comes from
28112025 9076 Expt Table 2025.xls — researcher summary (cross-check)
Something wrong on this page? Record a correction
Your correction is permanent: it survives every re-extraction and the field can no longer be changed by the system.
Field-by-field provenance (10 fields) — for auditors
1 extraction fragments · merged 2026-08-25 · 0 human-validated fields
Fix a wrong or missing extraction side-by-side with the original: expt-block--21
FieldSourceExtractorConf.
process_steps[0]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
process_steps[1]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
process_steps[2]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
samples[0]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
samples[1]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
samples[2]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
samples[3]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
samples[4]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
samples[5]28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
observations28112025 9076 Expt Table 2025.xls sheet 9076_Experiments, batch block '21', csv rows 72-86 qwen-tasks/extract-expt-block.md@unversionedhigh
Raw record JSON
{
  "record_id": "exp-9076-021",
  "project": "9076",
  "aliases": [
    "21",
    "LBN 21A",
    "LBN 21B",
    "LBN 21 C",
    "LBN 21D",
    "LBN 21E",
    "LBN 21F"
  ],
  "provenance": {
    "fragments": [
      "expt-block--21"
    ],
    "field_provenance": {
      "process_steps[0]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "process_steps[1]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "process_steps[2]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "samples[0]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "samples[1]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "samples[2]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "samples[3]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "samples[4]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "samples[5]": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      },
      "observations": {
        "source_file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
        "extractor": "qwen-tasks/extract-expt-block.md",
        "extractor_version": "unversioned",
        "extracted_date": "2026-08-20",
        "locator": "sheet 9076_Experiments, batch block '21', csv rows 72-86",
        "human_checked": true
      }
    },
    "last_merged": "2026-08-25"
  },
  "documents": [
    {
      "file": "docs/Project Expt Report/28112025  9076 Expt Table 2025.xls",
      "role": "summary_table",
      "link_basis": "alias match: 21",
      "link_status": "rule"
    }
  ],
  "validation": {
    "validated_fields": {},
    "corrections_applied": []
  },
  "process_steps": [
    {
      "name": "Step 1",
      "materials": [
        {
          "name": "Butanol EO - PO - 300 gm (Sunshield)",
          "descriptor": "HV-56",
          "quantity": 300,
          "unit": "g",
          "role": "reactant"
        },
        {
          "name": "Phosphorous pentaoxide",
          "quantity": 13.7,
          "unit": "g",
          "role": "reactant"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "temperature": "40",
          "time_h": 1,
          "verbatim": "Butanol EO - PO - 300 gm (Sunshield) HV-56, 300 g, 40 oC, 1 h"
        },
        {
          "seq": 2,
          "temperature": "65-75",
          "time_h": 4.5,
          "atmosphere": "N2",
          "verbatim": "Phosphorous pentaoxide, 13.7 g, 65-75 oC, 4.5 h, N2"
        }
      ],
      "conditions": {
        "temperature": "40; then 65-75",
        "atmosphere": "N2",
        "time_h": "1; then 4.5"
      },
      "results": [
        {
          "parameter": "A.V.",
          "value": 46.86,
          "verbatim": "AV-46.86"
        }
      ],
      "step": 1
    },
    {
      "name": "Step 2",
      "materials": [
        {
          "name": "Epomine SP- 018",
          "quantity": 90,
          "unit": "g",
          "role": "reactant"
        },
        {
          "name": "2 ethyl hexyl acrylate",
          "quantity": 210,
          "unit": "g",
          "role": "reactant"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "temperature": "80-82",
          "time_h": 6,
          "verbatim": "Epomine SP- 018, 90 g, 80-82 oC, 6 h"
        },
        {
          "seq": 2,
          "temperature": "80-83",
          "time_h": 2,
          "atmosphere": "N2",
          "verbatim": "2 ethyl hexyl acrylate, 210 g, 80-83 oC, 2 h, N2"
        }
      ],
      "conditions": {
        "temperature": "80-82; then 80-83",
        "atmosphere": "N2",
        "time_h": "6; then 2"
      },
      "results": [
        {
          "parameter": "unlabelled",
          "value": 256,
          "verbatim": "256"
        },
        {
          "parameter": "iodine value",
          "value": 70,
          "verbatim": "Iodine Value 70 / Time 2"
        },
        {
          "parameter": "iodine value",
          "value": 37.2,
          "verbatim": "Iodine Value 37.2 / Time 5.5"
        }
      ],
      "step": 2
    },
    {
      "name": "Step 3",
      "materials": [
        {
          "name": "Step-  1 product",
          "rm_pct": "80",
          "quantity": 160,
          "unit": "g",
          "role": "intermediate"
        },
        {
          "name": "Step -  2 Product",
          "rm_pct": "20",
          "quantity": 40,
          "unit": "g",
          "role": "intermediate"
        }
      ],
      "procedure": [
        {
          "seq": 1,
          "temperature": "60",
          "time_h": "605",
          "atmosphere": "N2",
          "verbatim": "Step-  1 product  (80), 160 g; Step -  2 Product  (20), 40 g; 60 oC, 605 h, N2"
        }
      ],
      "conditions": {
        "temperature": "60",
        "atmosphere": "N2",
        "time_h": "605"
      },
      "results": [],
      "step": 3
    }
  ],
  "samples": [
    {
      "sample_id": "LBN 21A",
      "preparation": "LBN 21 +3% AMP",
      "derived_from": [
        "21"
      ]
    },
    {
      "sample_id": "LBN 21B",
      "preparation": "LBN 21 +2% IPA",
      "derived_from": [
        "21"
      ]
    },
    {
      "sample_id": "LBN 21 C",
      "preparation": "LBN21 A + 2% mix xylene",
      "derived_from": [
        "LBN 21A"
      ]
    },
    {
      "sample_id": "LBN 21D",
      "preparation": "LBN 21 +4% mix xylene",
      "derived_from": [
        "21"
      ]
    },
    {
      "sample_id": "LBN 21E",
      "preparation": "LBN 21D +1% MIBK",
      "derived_from": [
        "LBN 21D"
      ]
    },
    {
      "sample_id": "LBN 21F",
      "preparation": "LBN 21 +2% ethyl cellosolve",
      "derived_from": [
        "21"
      ]
    }
  ],
  "observations": "Expt Table remarks: Strength/gloss for C black good/ Resolubility issue"
}