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Extracted values

Cited: Page 1 (highlighted). Compare with the original on the left. Press Enter to OK the highlighted value, or click OK / fix on any value. Experiment: exp-9076-030
aim highTo develop product equivalent to reference product temperature high55-60 atmosphere highN2 time high4h

Materials high

#sr_nonamesourcequantityunitmolecular_wtmolesmolar_ratio
0 1 Vicaspin LUB 1020 (R226011203) Bu- EO-PO HV-66.0/ MW-1100 Viswaat 190.0 gms 1100 0.17 1.0
1 2 P2O5 Commercial 9.715 gms 0.068 0.4
2 3 Epomine SP-018 Nippon 37.3 gms 100
3 4 2 ethyl hexyl acrylate 72.3 gms 184.3 0.39 100
4 5 Step- B reaction mass (20%) 32.0 gms
5 6 Step- A product 138.6 gms

Process steps high

StepCharged What happenedResults
Step 1
time 2 / 0.25 temperature 40-45 / 60-65 pressure N2
remarks: viscous clear mass
#TimeTempAtmWhat happened
1
To main reactor added Vicaspin LUB 1020 (R226011203) Bu- EO-PO HV-66.0/ MW-1100 under stirring and nitrogen atmosphere temp. 40 deg increased temp slowly with addition of P2O5
Step 2
time 2 / 0.25 temperature 40-45 / 55-60 pressure N2
remarks: AV-46.0, free acid 0.9
#TimeTempAtmWhat happened
1
To main reactor added Epomine SP-018- reaction mass held with slow addition of 2 ethyl hexyl acrylate, checked free acid at interval
Step 3
time 1 temperature 60-65 pressure N2
remarks: AV 45.9 Amine 33.7
#TimeTempAtmWhat happened
1
To main reactor added Step- B reaction mass (20%) and Step- A product, mixed till uniform

Outcome high

statusnot ok basisProduct hazy at RT, AV marginally above target. Repeat with reduced P2O5 charge. citationpdf/9076 Data for Raven POC project/Old ELN/Lab Batch 30.pdf, Page 1
More actions — correct a value · link · ignore
Action Field path Corrected value Cause Note permanent — survives every re-run
Raw fragment JSON
{
  "fragment_id": "qwen-extract--lab-batch-30--lbn-30",
  "source_file": "pdf/9076 Data for Raven POC project/Old ELN/Lab Batch 30.pdf",
  "derived_from": "ocr/Lab Batch 30",
  "locator": "Page 1",
  "extractor": "qwen-tasks/extract-fragment.md",
  "target_aliases": [
    "LBN 30"
  ],
  "document_role": "eln_report",
  "payload": {
    "aim": "To develop product equivalent to reference product",
    "eln_form": {
      "journal_version": "v2.0",
      "equipment": "Glass RBF with stirrer set up"
    },
    "materials": [
      {
        "sr_no": 1,
        "name": "Vicaspin LUB 1020 (R226011203) Bu- EO-PO HV-66.0/ MW-1100",
        "source": "Viswaat",
        "quantity": 190.0,
        "unit": "gms",
        "molecular_wt": 1100,
        "moles": 0.17,
        "molar_ratio": 1.0
      },
      {
        "sr_no": 2,
        "name": "P2O5",
        "source": "Commercial",
        "quantity": 9.715,
        "unit": "gms",
        "moles": 0.068,
        "molar_ratio": 0.4
      },
      {
        "sr_no": 3,
        "name": "Epomine SP-018",
        "source": "Nippon",
        "quantity": 37.3,
        "unit": "gms",
        "molar_ratio": 100
      },
      {
        "sr_no": 4,
        "name": "2 ethyl hexyl acrylate",
        "quantity": 72.3,
        "unit": "gms",
        "molecular_wt": 184.3,
        "moles": 0.39,
        "molar_ratio": 100
      },
      {
        "sr_no": 5,
        "name": "Step- B reaction mass (20%)",
        "quantity": 32.0,
        "unit": "gms"
      },
      {
        "sr_no": 6,
        "name": "Step- A product",
        "quantity": 138.6,
        "unit": "gms"
      }
    ],
    "process_steps": [
      {
        "step": 1,
        "time": "2 / 0.25",
        "temperature": "40-45 / 60-65",
        "pressure": "N2",
        "procedure": [
          {
            "action": "To main reactor added Vicaspin LUB 1020 (R226011203) Bu- EO-PO HV-66.0/ MW-1100 under stirring and nitrogen atmosphere temp. 40 deg increased temp slowly with addition of P2O5"
          }
        ],
        "remarks": "viscous clear mass"
      },
      {
        "step": 2,
        "time": "2 / 0.25",
        "temperature": "40-45 / 55-60",
        "pressure": "N2",
        "procedure": [
          {
            "action": "To main reactor added Epomine SP-018- reaction mass held with slow addition of 2 ethyl hexyl acrylate, checked free acid at interval"
          }
        ],
        "remarks": "AV-46.0, free acid 0.9"
      },
      {
        "step": 3,
        "time": "1",
        "temperature": "60-65",
        "pressure": "N2",
        "procedure": [
          {
            "action": "To main reactor added Step- B reaction mass (20%) and Step- A product, mixed till uniform"
          }
        ],
        "remarks": "AV 45.9 Amine 33.7"
      }
    ],
    "conditions": {
      "temperature": "55-60",
      "atmosphere": "N2",
      "time": "4h"
    },
    "critical_process_parameters": [
      {
        "sr_no": 1,
        "source": "Step-A",
        "time": 2,
        "temp": 45,
        "observation_details": "viscous clear mass"
      }
    ],
    "critical_parameters": [
      {
        "s_no": 1,
        "parameter": "av",
        "reference_value": 43.2,
        "value": 45.9
      },
      {
        "s_no": 2,
        "parameter": "aminev",
        "reference_value": 30.1,
        "value": 33.7
      }
    ],
    "conclusion": "Product hazy at RT, AV marginally above target. Repeat with reduced P2O5 charge.",
    "outcome": {
      "status": "not ok",
      "basis": "Product hazy at RT, AV marginally above target. Repeat with reduced P2O5 charge.",
      "citation": "pdf/9076 Data for Raven POC project/Old ELN/Lab Batch 30.pdf, Page 1"
    }
  },
  "field_confidence": {
    "aim": "high",
    "materials": "high",
    "process_steps": "high",
    "conditions": "high",
    "critical_process_parameters": "high",
    "critical_parameters": "high",
    "conclusion": "high",
    "outcome": "high"
  },
  "extractor_version": "direct-v1",
  "extracted_date": "2026-08-27"
}