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Extracted values

Cited: Page 1 (highlighted). Compare with the original on the left. Press Enter to OK the highlighted value, or click OK / fix on any value. Experiment: exp-9076-016
aim To develop product equivalent to reference product temperature 80-85 time 5h atmosphere N2

Materials

#sr_nonamesourcequantityunitmolecular_wtmolesmolar_ratiorolepurity_pct
0 1 Vicaspin LUB 1010 (R225100845) Bu- EO-PO HV-62.3/ MW-900 Viswaat 160.0 gms 900 0.18 1.0 reactant
1 2 P2O5 Commercial 7.548 gms 0.053 0.29 reactant
2 3 Epomine SP-018 Nippon 39.4 gms reactant 100
3 4 2 ethyl hexyl acrylate 67.0 gms 184.3 0.36 reactant 100
4 5 Step- B reaction mass (20%) 39.7 gms reactant
5 6 Step- A product 133.5 gms reactant

Process steps

StepCharged What happenedResults
Step 1
time 3 temperature 45-50 pressure N2
remarks: clear mass
#TimeTempAtmWhat happened
1
To main reactor added Vicaspin LUB 1010 (R225100845) Bu- EO-PO HV-62.3/ MW-900 under stirring and nitrogen atmosphere temp. 40 deg increased temp slowly with addition of P2O5
Step 2
time 0.5 / 3 / 0.5 temperature 55-60 / 65-70 / 85-90 pressure N2
remarks: AV-50.7, free acid 0.5
#TimeTempAtmWhat happened
1
To main reactor added Epomine SP-018- reaction mass held with slow addition of 2 ethyl hexyl acrylate, checked free acid at interval
Step 3
time 1-2 temperature 55-60 pressure N2
remarks: AV 40.8 Amine 33.5
#TimeTempAtmWhat happened
1
To main reactor added Step- B reaction mass (20%) and Step- A product, mixed till uniform

procedure summary

Step A: Added Vicaspin LUB 1010 under stirring and nitrogen, increased temp slowly with addition of P2O5. Step B: Added Epomine SP-018, held with slow addition of 2 ethyl hexyl acrylate, checked free acid. Step C: Added Step B reaction mass and Step A product, mixed till uniform.

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Raw fragment JSON
{
  "fragment_id": "qwen-extract--lab-batch-16--lbn-16",
  "source_file": "pdf/9076 Data for Raven POC project/Old ELN/Lab Batch 16.pdf",
  "derived_from": "ocr/Lab Batch 16",
  "locator": "Page 1",
  "extractor": "qwen-tasks/extract-fragment.md",
  "target_aliases": [
    "LBN 16"
  ],
  "document_role": "eln_report",
  "payload": {
    "aim": "To develop product equivalent to reference product",
    "eln_form": {
      "journal_version": "v3.0",
      "equipment": "Glass RBF with stirrer set up"
    },
    "materials": [
      {
        "sr_no": 1,
        "name": "Vicaspin LUB 1010 (R225100845) Bu- EO-PO HV-62.3/ MW-900",
        "source": "Viswaat",
        "quantity": 160.0,
        "unit": "gms",
        "molecular_wt": 900,
        "moles": 0.18,
        "molar_ratio": 1.0,
        "role": "reactant"
      },
      {
        "sr_no": 2,
        "name": "P2O5",
        "source": "Commercial",
        "quantity": 7.548,
        "unit": "gms",
        "moles": 0.053,
        "molar_ratio": 0.29,
        "role": "reactant"
      },
      {
        "sr_no": 3,
        "name": "Epomine SP-018",
        "source": "Nippon",
        "quantity": 39.4,
        "unit": "gms",
        "purity_pct": 100,
        "role": "reactant"
      },
      {
        "sr_no": 4,
        "name": "2 ethyl hexyl acrylate",
        "quantity": 67.0,
        "unit": "gms",
        "purity_pct": 100,
        "molecular_wt": 184.3,
        "moles": 0.36,
        "role": "reactant"
      },
      {
        "sr_no": 5,
        "name": "Step- B reaction mass (20%)",
        "quantity": 39.7,
        "unit": "gms",
        "role": "reactant"
      },
      {
        "sr_no": 6,
        "name": "Step- A product",
        "quantity": 133.5,
        "unit": "gms",
        "role": "reactant"
      }
    ],
    "conditions": {
      "temperature": "80-85",
      "time": "5h",
      "atmosphere": "N2"
    },
    "procedure_summary": "Step A: Added Vicaspin LUB 1010 under stirring and nitrogen, increased temp slowly with addition of P2O5. Step B: Added Epomine SP-018, held with slow addition of 2 ethyl hexyl acrylate, checked free acid. Step C: Added Step B reaction mass and Step A product, mixed till uniform.",
    "process_steps": [
      {
        "step": 1,
        "time": "3",
        "temperature": "45-50",
        "pressure": "N2",
        "procedure": [
          {
            "action": "To main reactor added Vicaspin LUB 1010 (R225100845) Bu- EO-PO HV-62.3/ MW-900 under stirring and nitrogen atmosphere temp. 40 deg increased temp slowly with addition of P2O5"
          }
        ],
        "remarks": "clear mass"
      },
      {
        "step": 2,
        "time": "0.5 / 3 / 0.5",
        "temperature": "55-60 / 65-70 / 85-90",
        "pressure": "N2",
        "procedure": [
          {
            "action": "To main reactor added Epomine SP-018- reaction mass held with slow addition of 2 ethyl hexyl acrylate, checked free acid at interval"
          }
        ],
        "remarks": "AV-50.7, free acid 0.5"
      },
      {
        "step": 3,
        "time": "1-2",
        "temperature": "55-60",
        "pressure": "N2",
        "procedure": [
          {
            "action": "To main reactor added Step- B reaction mass (20%) and Step- A product, mixed till uniform"
          }
        ],
        "remarks": "AV 40.8 Amine 33.5"
      }
    ],
    "critical_process_parameters": [
      {
        "sr_no": 1,
        "source": "Step-A",
        "time": "3",
        "temp": "50",
        "observation_details": "clear mass"
      },
      {
        "sr_no": 2,
        "source": "Step-B",
        "time": "0.5",
        "temp": "80",
        "observation_details": "free acid < 0.5 endpoint check"
      }
    ],
    "critical_parameters": [
      {
        "s_no": 1,
        "parameter": "av",
        "reference_value": "43.2",
        "value": "40.8"
      },
      {
        "s_no": 2,
        "parameter": "aminev",
        "reference_value": "30.1",
        "value": "33.5"
      }
    ],
    "field_confidence": {
      "aim": "high",
      "materials": "high",
      "conditions": "high",
      "procedure_summary": "high",
      "critical_parameters": "high"
    }
  },
  "extractor_version": "direct-v1",
  "extracted_date": "2026-08-27",
  "field_confidence": {}
}